Orthogonal optimisers such as Muon can substantially accelerate large language model pretraining relative to Adam, yet the mechanism remains incompletely understood. We investigate this through an out-of-sample spectral probing analysis of Transformer loss landscapes. At checkpoints along real training trajectories, we decompose each momentum buffer into its singular directions and estimate the loss-optimal step size along each direction on held-out data. The resulting spectral profile is anisotropic yet stable across batches and training stages, and consistent across the optimisers and model scales: a volatile head operating at the Edge-of-Stability supports a much smaller step size than the tolerant bulk, which permits substantially larger steps. This profile provides a unified spectral allocation account of why Muon outperforms Adam, which outperforms SGD. It also exposes a limitation of Muon's uniform scaling: it still underutilises the bulk. Guided by this finding, we introduce Spectral-Aware Muon (SAMuon), which holds the head at the Muon scale and amplifies the bulk using a static spectral prior. We provide two variants: the complete SAMuon follows the measured profile using a low-rank randomised SVD and the simplified SAMuon-lite uses a two-level approximation via rank-one power iteration. Neither method adds persistent optimiser state or notable extra FLOPs beyond Muon at scale, and the idealised exact-whitening versions of both retain Muon's asymptotic convergence rate under standard assumptions. Across "modded-nanogpt" models from 124M to 1B parameters, both variants outperform tuned AdamW and Muon (Scion implementation) baselines in all evaluated model-scale and batch-size configurations. SAMuon requires 13.3% to 24.0% fewer training tokens to reach the same validation loss as Muon, while SAMuon-lite retains most of this gain with near-zero wall-clock overhead.